1.

CN^(-) ion is known but CP^(-) ion is not known.

Answer»

Solution :Due to smaller SIZE and HIGHER electrongeativity of N than of P, N can form `ppi-ppi` multiple BONDS with C and hence forms `CN^(-)` ion. On the other hand, due to bigger size and lower electronegativity of P than that of N, P does not form multiple bonds with C and hence does not form `CP^(-)` ion.
`underset(("Exists"))(""^(-):C-=N)""underset(("Does not EXIST"))(""^(-):C-=P)`


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