1.

Cobalt (III) chloride forms several octahedral complexes with amonia. Which of the following will not give test for chloride ions with silver nitrate at `25^@C`?A. (a) `CoCl_3*5NH_3`B. (b) `CoCl_3*6NH_3`C. (c) `CoCl_3*3NH_3`D. (d) `CoCl_3*4NH_3`

Answer» Correct Answer - C
For octahedral complexes, coordination number is 6. Hence, `CoCl_3 diamond 3NH_3`, i.e., `[Co(NH_3)_3diamondCl_3]` will not ionize and will not give test for `Cl^(-)` ions with silver nitrate.


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