1.

Comment on the structure of beryllium chloride

Answer»

Solution :Beryllium CHLORIDE has a chain structure in the solid state due to the formation of coordinate bond between Cl and Be of DIFFERENT molecules. Hybridisation of Be in it is sp. In vapour phase `BeCl_(2)` tends to form a chloro-bridged DIMER in which hybridisation of Be is `sp^(2)`.

At high temperatures (above 1200K) dimer is DISSOCIATED to form LINEAR monomer. In monomer hybridisation of Be is sp. `Cl-Be-Cl`.


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