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Compound (A) (C_8H_8O) on treatment with NH_2OH.HCI gives (B) and (C) rearrange to give (D) and (E), respectively, on treatment with acid. (B), (C),(D)and (E) are all isomers of molecular formula (C_8H_9NO) . When (D) is boiled with alcoholic KOH, an oil (F) (C_6H_7N) separates out. (F) reacts with CH_3COCI to give back (D). On the other hand. (E) on boiling with alkali followed by acidification gives a white solid (G) (C_7H_6O_2). Identify (A)to (G). |
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