InterviewSolution
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InterviewSolution
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Compounds that formally contain `Pb^(4+)` are easily reduced to `Pb^(+)` .The stability of the lower oxidation state is due to `"…….."` . |
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Answer» Correct Answer - Inert pair effect Compounds that formally contain `Pb^(4+)` are easily reduced to `Pb^(2+)`. The stability of the lower oxidation state is due to inert pair effect. In the periodic table, inert pair effect increases down the group. So in group `14`, the stability of smaller oxidation state of `+2` goes on increasing down the group. `Pb^(4+)` has an oxidising nature and `Br^(ɵ)` and `I^(ɵ)` have reducing nature, so `Pb^(4+)` is reduced to `Pb^(2+)`. `Pb^(4+)+2Br^(ɵ) rarr Pb^(2+)+Br_(2)` `Pb^(4+)+2I^(ɵ) rarr Pb^(2+)+I_(2)` |
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