1.

Compressibility factor, Z, of a gas is given as Z=(pV)/(nRT)(i) What is the value of Z for an ideal gas ?For real gas what will be the effect on value of Z above Boyle.s temperature ?

Answer»

Solution :(i) For ideal gas, compressibility factor, Z = 1.
(II) Above Boyle.s temperature, real gases show positive deviation.
So, `Z gt 1`
Note : FOLLOWING important points come out from the compressibility factor, `Z=(PV)/(nRT)`
(i) For ideal Z = 1 at all TEMPERATURES and PRESSURE because pV = nRT.
(ii) At very low pressure all gases shown have `Z ~=1` and behave as ideal gas.
(iii) At high pressure, all the gases have `Z gt 1` These are more difficult to compress.
(iv) At intermediate pressures most gases have `Z lt 1`.


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