1.

Consider the compounds, BCl_(3)" and "C"C"l_(4). How will they behave with water ? Justify.

Answer»

Solution :B ATOM in `BCl_3` has only six electrons. Thus, `BCl_3` is an electron-deficient MOLECULE and ACCEPTS a pair of electrons DONATED by water. Therefore, when treated with water, `BCl_3` undergoes hydrolysis to form boric acid and HCI.
`BCl_3 + 3H_2 O to H_3 BO_3 + 3HCL`
On the other hand, C atom in `C Cl_4` possesses an octet and has no tendency to accept or donate a pair of electrons. Hence, it does not react with water.


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