Consider the following two equilibrium established together in a closed container A(s)hArr2B(g)+3C(g) , K_(P_(1) A(s)hArr3D(g) , K_(P_(2) Starting with only A(s), molar ratio of B(g) & D(g) at equilibrium is found to be in a ratio 1:6 determine (K_(P_(2)))/(8K_(P_(1)))

Consider the following two equilibrium established together in a close

1.	Consider the following two equilibrium established together in a closed container A(s)hArr2B(g)+3C(g) , K_(P_(1) A(s)hArr3D(g) , K_(P_(2) Starting with only A(s), molar ratio of B(g) & D(g) at equilibrium is found to be in a ratio 1:6 determine (K_(P_(2)))/(8K_(P_(1)))
Answer» Solution :`P_(B):P_(D)=1:6` LET the PARTIAL at pressure of `B` EQ. be `P_(0)` `K_(p_(1))=(P_(0))^(2)((3P_(0))/(2))^(3)` `K_(p_(2))=(6P_(0))^(3)` `(K_(p_(2)))/(K_(p_(1)))=(6^(3))/(((3)/(2))^(3))=64` `(K_(p_(2)))/(8K_(p_(1)))=(64)/(8)=8`