1.

Consider the Hofmann ammonolysis reaction : `R-X +ddotNH_(3)rarr underset(1^(@) amine)(HX + RNH_(2)) overset(R-X)underset(373K)rarr` If `R = Me_2 CH-(isopropyl)`, the correct order of basic character of the above amines in aqueous medium is :A. `3^@ gt 2^@ gt 1^@ gt NH_3`B. `NH_3 gt 1^@ gt 2^@ gt 3^@`C. `1^@ gt 2^@ gt NH_3 gt 3^@`D. `1^@ gt NH_3 gt 2^@ gt 3^@`

Answer» Correct Answer - D
(d) In gaseous or nonpolar solvent, the basic order is `3^@ gt 2^@ gt 1^@ gt NH_3`.


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