1.

Consider the statements : I . Bond length in N_(2)^(+) is 0.002 Å greater than in N_(2) II. Bond length in NO^(+) is 0.09 Å less than in NO III. O_(2)^(2-) hasshorter bond length than O_(2) which of the following statements are ture ?

Answer»

I and II
II and III
I, II and III
I and III

Solution :Bond order of `N_(2)` is 3 and that of `N_(2)^(+)` is 2.5 .
Greater the bond order , shorter is the bond length
HENCE order of NO is 2.5 and that of `NO^(+)` is 3 THUS , bond length of `NO^(+)` is shorter . Hence ,II is TRUE
Bond order of `O_(2)`is 2 while that ` O_(2)^(2-)` is 1. Thus,
bond length of `O_(2)` is shorter . Hence , III is not ture .


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