InterviewSolution
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InterviewSolution
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Crystal field stabilization energy for high spin `d^4` octahedral complex isA. `-1.8 Delta_(0)`B. `-1.2 Delta_(0)`C. `-1.6 Delta_(0)`D. `-0.8 Delta_(0)` |
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Answer» Correct Answer - D The electronic configuration of `d^(4)` complex is `t_(2g)^(3) e_(g)^(1)`. The CFSE is given by CFSE `= (-0.4 x + 0.6 y) Delta_(0)` where, x is the number of electrons in `t_(2)` and y is the number of electrons in `e_(g)`. Therefore, the CFSE is given by `CFSE = [0.4 xx 3] + [0.6 xx 1] Delta_(0) = [-1.2 + 0.6]Delta_(0) = 0.6Delta_(0)` |
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