1.

CsCl crystallises in body - centred cubic lattice. If 'a' is its edge length the which of the following expressions is correct ?

Answer»

` r_(Cs+)+ r_(Cl^(-)) = sqrt3 a `
`r_(Cs^(+)) + r_(Cl^(-)) = 3A `
` r_(Cs^(+) + r_(Cl^(-)) = (3a)/2`
`r_(Cs^(+)) + r_(Cl^(-))= sqrt3/2 a `

SOLUTION :In body-centred cubic (BCC) , oppositely chargedions touch each other along the body diagonal .

Body diagonal , ` AE = 2r_(Cs^(+)) + 2r_(Cl^(-))`
But body diagonal = ` SQRT 3a `
( From right angled` DeltaCDE, CE =sqrt(a^(2) +a^(2))= sqrt2a `
From right angled ` Delta ACE`
` AE = sqrt( AC^(2)+ CE^(2)) = sqrt(a^(2) + 2a^(2)) = sqrt(3a^(2)) = sqrt3 a `)
`2(r_(Cs^(+)) +r_(Cl^(-)) = sqrt3 a or r_(Cs) + r_(Cl^(-)) = sqrt3/2 a `


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