1.

CsCl had bcc arrangement and its uint cell edge length is 400 pm. Calculate the interionic distance in CsCl.

Answer»

Solution :The bcc arrangement iof CsCl, wehre balck cricle is ` Cs^(+)` ion and colured circles are` Cl^(-) ` ions. The aim is to find half of the body diagonal AE. If the EDGE of the UNIT cell is 'a' then,
` CE = sqrt(a^(2) +a^(2)) = SQRT2 a`
` AE = sqrt((sqrt2a)^(2) + a^(2)) = sqrt3 a = sqrt3 XX 400`
Interionic distanace = `1/2 AE = sqrt 3 xx 200 = 346.4 ` pm


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