1.

CsClcrystallises in body-centred cubic lattice. If 'a' is its edge length then which of the following expressions is correct ?

Answer»

`r_(Cs^+)+r_(Cl^-)=sqrt3a`
`r_(Cs^+)+r_(Cl^-)=3a`
`r_(Cs^+)+r_(Cl^-)="3a"/2`
`r_(Cs^+) + r_(Cl^-)=sqrt3/2 a`

Solution :In body-centred cubic (BCC), oppositely CHARGED ions touch each other ALONG the body diagonal

`THEREFORE` Body diagonal, AE=`2r_(Cs^+)+ 2r_(Cl^-)`
But body diagonal =`sqrt3a`
(From right angled `triangleCDE`, CE=`sqrt(a^2+a^2)=sqrt2a`
From right angled `TRIANGLE ACE` , `AE=sqrt(AC^2+CE^2)=sqrt(a^2+2a^2)=sqrt(3a^2)=sqrt3a`)
`therefore 2(r_(Cs^+)+r_(Cl^-))=sqrt3a` or `r_(Cs^+) +r_(Cl^(-))=sqrt3/2a`


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