1.

Decreasing order of enol content of the following compound in liquid phase I) CH_(3)-overset(O)overset(||)C-CH_(2)-overset(O)overset(||)C-O-EtII) CH_(3)-overset(O)overset(||)C-CH_(2)-overset(O)overset(||)C-CH_(3) III) Ph-overset(O)overset(||)C-CH_(2)-overset(O)overset(||)C-Ph

Answer»

I `GT` II `gt` III `gt` IV
III `gt` II `gt` I `gt` IV
III `gt` II `gt` IV `gt` I
II `gt` III `gt` I `gt` IV

Solution :`UNDERSET("less stable")(CH_(3)-overset(OH)overset(|)C=CH-overset(O)overset(||)C-O)et`
`underset("stable")(CH_(3)-overset(OH)overset(|)C=CH-overset(O)overset(||)C-)CH_(3),""underset("More stable")(Ph-overset(OH)overset(|)C=CH-overset(O)overset(||)C-)Ph`

Anti -Aromatic
LEAST Stable
KETO group is more with drawing group than ester group.


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