1.

Define and explain the term, enthalpy or heat of reaction.

Answer»

Enthalpy or heat of reaction : The enthalpy of a chemical reaction is the difference between the sum of the enthalpies of products and that of the reactants with every substance in a definite physical state and in the amounts (moles) represented by the coefficients in the balanced equation.

Explanation : Consider the following general reaction,

aA + bB → cC + dD

The heat of the reaction ΔH is the difference in sum of enthalpies of products and sum of enthalpies of reactants.

∴ ΔH = ΣHproduts – ΣHreactants 

= [cHc + dHD] – [aHA + bHB

= ΣPH – ΣRZ

Where H represents enthalpy of the substance. For endothermic reaction, 

ΔH is positive, (ΔH > 0).

For exothermic reaction, 

ΔH is negative, 

(ΔH < 0).



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