1.

Define conductivity and molar conductivity for the solution of an electrolyte. Discuss their variation with concentration.

Answer»

Conductivity : The reciprocal of resistivity is conductivity. Conductivity is the conductance of the electrolytic solution (due to the movement of ions and electrons) of one metre length and unit area of cross section. Mathematically, conductivity, K = 1/p
Conductivity varies with concentration. As the number of ions per cm3 of solution decreases, conductivity decreases.

Molar conductivity : The conductivity of one molar electrolytic solution is termed as molar conductivity. Mathematically,
Molar conductivity (Δm) = k/c,
where c = concemtration (in mol m-3)
K = conductivity (in S m-1)
It should be noted that for strong electrolytes there is only a small increase in Δm value with dilution. However for weak electrolytes, there is a large increase in Δm value with dilution.



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