1.

Delta_(f)U^(@) of formation of CII_(4)(g) at certain temperature is -393 kJ"mol"^(-1).The value of Delta_(f)H^(@) is

Answer»

zero
`lt Delta_(F)U^(@)`
`gtDelta_(f)U^(@)`
equal to `Delta_(f)U^(@)`

Solution :`Delta_(f)H^(@) = Delta_(f)U^(@) + Delta_(g)RT`
For the reaction,
`C(s) + 2H_(2)(g) to CH_(4)(g)`
`therefore Deltan_(g) = 1 -2 = -1`
`therefore Delta_(f)H^(@) = Delta_(f)U^(@) - 1RT`
or `Delta_(f)U^(@) = Delta_(f)H^(@) + RT`
or `Delta_(f)H^(@) lt Delta_(f)U^(@)`.


Discussion

No Comment Found