1.

Determine the solubilities of silver chromate, barium chromate, ferric, hydroxide, lead, chloride and mercurous iodide at 298 K. Given K_(sp) values : Ag_(2)CrO_(4)=1.1xx10^(-12), BaCrO_(4)=1.2xx10^(-10), Fe(OH)_(3)=1.0xx10^(-38), PbCl_(2)=1.6xx10^(-5), Hg_(2)I_(2)=4.5xx10^(-29) Determine also the molarities of individual ions.

Answer»


Solution :`{:(Ag_(2)CrO_(4)HARR 2"Ag"^(+)+CrO_(4)^(2-),K_(sp)=(2s)^(2)(s)=4s^(3)"," :. s^(3)=K_(sp)//4,,),(s""2s"" s""=(1.1xx10^(-12))//4=0.275xx106(-12)=2.75xx10^(-13),,):}`
`:. 3 log s = log (2.75xx 10^(-13))=-13+0.4393=-12.5607`
or` log s = - 4.1869 = bar(5).8131`
`:. s= 6.5xx10^(-5) ` mol `L^(-1)`
`[Ag^(+)]=2xx6.5xx10(-5)=13.0xx10^(-5)M = 1.30 xx 10^(-4)M`
`[CrO_(4)^(2-)] = 6.5xx10^(-5)M`
For other salts, PROCEED exactly in similar manner .


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