1.

Discuss briefly the similarities between Be and AI.

Answer»

Solution :(i)nBeryllium and aluminiem have same electrnegativily VALUES.
(ii) Their changesper unit are Is closer.
(iii) `BeCI_(2)` and `AICI_(3)` forms dimeric structure. Both are soluble in organic solvents and are strong Lewis acids.
(iv) `Be(OH)_(2)` and `AI(OH)_(3)` dissolves in EXCESS alkali to give beryllate icon `[Be(OH)_(4)]^(2)` and alumianteion `[AI(OH)_(4)]`, respectvely.
(v) Be and AI ions have stromg TENDECY to form complexes. `BeF_(4)^(2)` and `AIF_(6)^(3)`.
(VI) Both `Be(OH)_(2)` and `AI(OH)_(3)` areamphoteric in nature.
(VII) Both beryllium and aluminium are rendred passive by nitric acid.


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