1.

Discuss the role of Lewis acids in the preparation of aryl bromides and chlorides in the dark.

Answer»

Solution :Lewis ACIDS help to generate electrophile during the bromination and chlorination.
`CI_(2) + FeCl _(3) to FeCl_(4)^(-) + underset(underset("(Electrophile)")("Chloronium ion"))(Cl^(+))`
`Br_(2)+ FeBr_(3) to FeBr_(4)^(-) + underset(underset("(Electrophile)")("Bromonium ion"))(Br^(+))`
The electrophile then attacks the benzene ring to FORM a CARBOCATION, which loses a PROTON to form aryl CHLORIDE or aryl bromide.


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