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Discuss the role of Lewis acids in the preparation of aryl bromides and chlorides in the dark. |
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Answer» Solution :Lewis ACIDS help to generate electrophile during the bromination and chlorination. `CI_(2) + FeCl _(3) to FeCl_(4)^(-) + underset(underset("(Electrophile)")("Chloronium ion"))(Cl^(+))` `Br_(2)+ FeBr_(3) to FeBr_(4)^(-) + underset(underset("(Electrophile)")("Bromonium ion"))(Br^(+))` The electrophile then attacks the benzene ring to FORM a CARBOCATION, which loses a PROTON to form aryl CHLORIDE or aryl bromide. |
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