1.

Distinguish between the following pair of compounds:(i) Aniline and Benzylamine.(ii) Methylamine and Dimethylamine.

Answer»

(i) 

ExperimentAnilineBenzylamine
Azo dye test: Dissolve the amine in HCl, cool it and then add cold aqueous solution of NaNO2 and then solution of β - naphtholA brilliant orange red dye is observed.No dye is formed.

(ii)

ExperimentMethylamineDimethylamine
Carbylamine test: To the organic compound add chloroform and ethanolic potassium hydroxide and heatA foul smelling substance (isocyanide) No reaction.



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