1.

Draw the M.O diagram for oxygen molecule calculate its bond order and show that O_(2) is paramagnetic.

Answer»

Solution :(i) ELECTRONIC configuration of O atom is `1s^(2)2s^(2)2p^(4)`
(ii) Electronic configuration of `O_(2)` molecule is
`sigma 1s^(2)" "sigma**1s^(2)" "sigma2s^(2)" "sigma**2s^(2)" "sigma2p_(x)^(2)" "pi2p_(Z)^(2)" "pi**2p_(y)^(1)" " pi**2p_(z)^(1)`
(iii) Bond order `=(N_(B)-N_(a))/(2)=(10 - 6 )/(2)=2`
(iv) Mole cule has two unpaired electrons, hence it is paramagnetic.


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