1.

During estimation of nitrogen present in an organic compound by Kjeldahl's method, the ammonia evolved from 0.5g of the compound in Kjeldahl's estimation of nitrogen, neutralized 10 mL of 1M H_(2)SO_(4). Find out the percentage of nitrogen in the compound

Answer»

Solution :Mass of compound = m= 0.5g
10 ML 1M `H_(2)SO_(4)` = 20 mL 1M `NH_(3)`
100ML `1M NH_(3)`= 14 nitrogen
`:.` 20 mL `1M NH_(3) = (20 mL xx 14g)/(1000 mL)`
= 0.28g nitrogen
`:. % N = ("weight of " N xx 100)/("mass of compound")`
`= (0.28 xx 100)/(0.5) = 56%`


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