1.

Each question given below contains STATEMENT -1 (Assertion) and STATEMENT -2 (Reason). It has four choice (a), (b), ( c ) and (d)out of which ONLY ONE is correct . Choosethe correct option as under : Statement -1 Adding inert gas to dissociation equilibrium of N_(2)O_(4)at constant pressure and temperature increases the dissociation. Statement -2. Molar concentrations of the reactants and products decrease .

Answer»

(a) Statement -1 is True , Statement-2 is true , Statement -2 is the correct explanation of Statement-1
(b) Statement -1 is True , Statement -2 is not a correctexpanation of Statement -1 .
(c ) Statement-1 is True, Statement -2 is False .
(d) Statement -1 is False , Statement -2 is True .

Solution :To Keep the pressure constant , volume WOULD INCREASE. As a RESULT , molar concentration of each reactant and product will decrease.
For `N_(2) O_(4) HARR 2 NO_(2) , K = ([NO_(2)]^(2))/([N_(2) O_(4)]`
To keep K constant , `N_(2)O_(4)`should decrease more.


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