1.

Electronegativity of carbon atoms depends upon their state of hybridisation. In which of the following compounds, the carbon marked with asterisk is most electronegative?

Answer»

`CH_(3)-CH_(2) - ""^(**)C H_(2)-CH_(3)`
`CH_(3)- ""^(**)C H= CH- CH_(3)`
`CH_(3)- CH_(2)- C -= ""^(**)C H`
`CH_(3)-CH_(2)-CH= ""^(**)C H_(2)`

SOLUTION :(C ) `CH_(3)-CH_(2) - underset(underset(underset(sp)(uarr))(-))(C )-= underset(underset(underset("sp carbon")(uarr))(-))(""^(**)C)H`
(A)`CH_(3)- CH_(2) - underset(underset(underset(sp^(3)"carbon")(uarr))(-))(""^(**)C)H_(2)-CH_(3)`
(B) `CH_(3) - underset(underset(underset(sp^(2)"carbon")(uarr))(-))(""^(**)C)H= CH-CH_(3)`
(D) `CH_(3)-CH_(2)-CH= underset(underset(underset(sp^(2)"carbon")(uarr))(-))(""^(**)C)H_(2)`

but electronegativity `prop` % of s-orbital.
`THEREFORE` sp carbon is MAXIMUM electronegative.


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