1.

Elevation in boiling point of an aqueous solution of urea is `0.52 ( k_(b) "for water"=0.52K"molality"^(-1))`. The mole fraction is urea in this solution is :A. `0.98`B. `0.0567`C. `0.943`D. `0.02`

Answer» Correct Answer - D
`Delta T = K_(b) xx "molality"`
`0.52 = 0.52 xx "molality"`
`:. (n)/(W) xx 1000 = 1`
`(nxx1000)/((W)/(M) xx M) = 1`
or `(n)/(N) = (18)/(1000)`
or `(N+n)/(N) = (1018)/(1000) = 1.018`
`:. (N)/(n+N) = 0.98`,
`:. (n)/(n+N) = 0.02`


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