1.

Energy of an electron in the ground state of the hydrogen atom is -2.18 xx 10^(-18) J. Calculate the ionization enthalpy of atomic hydrogen in terms of J mol^(-1).

Answer»

Solution :Ionization enthalpy is the amount of energy REQUIRED to removed the ELECTRON from ground state to infinity.
Energy of electron ground state ` = -2.18 xx 10^(-18) J`
Energy of electron at infinity = 0
Energy required to remove electron ` = - (2.18 ) xx 10^(-18) J = 2.18 xx 10^(-18) J`
Amount of energy required to remove 1 mol of electrons from 1 mol of H atom
` = 2.18 xx 10^(-18) J xx 6.022 xx 10^(23) `per mol
` :. `Ionization enthalpy of hydrogen
` = 13.130 xx 10^(5) J " mol "^(-1)`
` = 13.13 xx 10^(5) J " mol "^(-1)`
NOTE: Ionisation enthalpy is always POSITIVE.


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