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Energyof anelectron in the groundstate of thehydrogenatom is -2 . 18 xx 10^(-18)J. Calculatetheionizationenthalpyof atomichydrogenin termsof kJ mol^(-1)

Answer»

SOLUTION :Ionizationenergyis theamount ofenergyrequired toremovethe electronfrom thegroundstate to infinity.
Now, energy ofthe electronin the groundstate = -`2.18 xx 10^(-15) J`
ENERGYOF the electronat affinity=0
The energyrequiredto removedand electronin theground state ofhydrogen atom
=0 - (its energyin thegroundstate ) = - `(-2 .18 xx 10^(-18)J )= 2. 18 xx 10^(-18) J`
`:.` Ionizationenthalpy per MOLEOF HYDROGENATOMS `= (2.18 xx 10^(18)xx 6.02 xx 10^(23))/(1000) kJ`
`= 1312 . 36 kJmol^(-1)= 1312 .36xx 10^(3)J mol^(-1)`


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