1.

Enthalpy and Entropy changes of two reactions are given below: Find out whether they are spontaneous or not at 27°C. Justify. 1. ∆H = 26 kJ/mole, ∆S = 8.3 J/K/mole 2. ∆H = -393.4 kJ/mole, ∆S = 6 J/K/mole

Answer»

1. ∆G = ∆H -T∆S 

= 26000 – 300 × 8.3 

= 23.510 

Since ∆G is positive, the process is non-spontaneous.

2. ∆G = ∆H -T∆S 

= -393400 – 300 × 6 

= -391600 

Since ∆G is negative, the process is spontaneous.



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