1.

Enthalpy change of CH_(4)+(1)/(2) O_(2) rarr CH_(3) OH is negative . If enthalpy of combustion ofCH_(4) andCH_(3)OH are x and y respectively, then which relation is correct ?

Answer»

`x gt y`
`x lty`
`x=y`
`x GEY`

Solution :(i) `CH_(4) + 2O_(2)rarr CO_(2)+ 2H_(2)O , DeltaH= x`
(ii) `CH_(3) OH + (3)/(2) O_(2) rarr CO_(2)+ 2H_(2)O, DeltaH =y`
(i) - (ii) GIVES `DeltaH ` for the given reaction, i.e., `DeltaH = x-y `.As it is -ve , `x lty`


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