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Entropy change for reversible phase transition at constant pressure P and temperatureT is calculated by the formula DeltaS=(DeltaH)/(T), where DeltaH is the enthalpy change for phase transition. For irreversible phase transition DeltaSgt(DeltaH)/(T). Consider a phase transition. Sn("white",s)iffSn("grey,s") DeltaH^(@) at 1 atm and 300K=-2 kJmol^(-1) The equilibrium temperature at 1 atm is 400 K. Assume C_(p,m) of Sn (white,s) and Sn(grey,s) are equal. DeltaS^(@) for above phase transition at 1 atm and 300K is : |
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Answer» `-5JK^(-1)mol^(-1)` |
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