1.

Equal volumes of 1M KMnO_4 and 1M K_2Cr_2O_7 solution are allowed to oxidise Fe^(2+) ions to Fe^(3+) ions in acidic medium. The number of moles of Fe^(2+) ions oxidised in the two cases are in the ratio:

Answer»

`1:1`
`3:1`
`5:6`
`6:5`

Solution :Eq. mass of KMn04 in acidic medium =`("Mol. mass")/5`
Eq. mass of `K_2Cr_2O_7` in acidic medium `=("Mol. mass")/56`.
Equalvolumesof1M`KMnO_4`and1M `K_2Cr_2O_7`willhavegramequivalentsin the ratio of 5 : 6. Hence, number of GRAM equivalents (moles, as the eq. mass of `FE^(2+)` = mol. mass) of `Fe^(2+)` IONS oxidised in the TWO cases will also be in the ratio of `5 : 6`.


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