1.

equilibrium at atmospheric pressure t is found to be dissociated to the extent of 80%phoIf a given quantity of phosphorus pentachloride is heated to 250°C and allowed tos increased so thasphorous trichloride and chlorine. If now, the pressure on this mixture is increasfinemally the equilibrium mixture occupies only one half of its original volume (tmaintained constant)(a) What will be the % dissociation at the new pressure?(b) What will be the effect of adding He gas keeping the volume fixed atV/2.

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