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Estimate the mean free path for a water molecule in water vapour at 373.The diameter of the molecule is 2xx10^(10)m, and at STP number of molecules per unit volume is 2.7xx10^(25)m^(-3)

Answer»

Solution :The number DENSITY (n) is inversely proportional to absolute temperature.
`therefore nalpha(1)/(T)implies(n_(273))/(n_(273))=(273/(373)),n_(373)=n_(273)xx(273)/(373)`
`n_(373)=2.7xx10^(25)xx(273)/(373)=2xx10^(25)m^(-3)`
Given d=`2xx10^(-10)m`
Hence ,mean FREE path `LAMBDA=(1)/(sqrt(E)pid^(2)n)`
`=(1)/(sqrt(2)xx3.14xx(2xx10^(-10))^(2)xx2xx10^(25))=4xx10^(-7)m`


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