1.

Ethanol when reacted with PCl_(5) gives A, POCl_(3) and HCl. A reacts with silver nitrite to form B (major product) and AgCl. A and B respectively are

Answer»

`C_(2)H_(4)Cl` and `C_(2)H_(5)OC_(2)H_(5)`
`C_(2)H_(6)` and `C_(2)H_(5)OC_(2)H_(5)`
`C_(2)H_(5)Cl` and `C_(2)H_(5)NO_(2)`
`C_(2)H_(6)` and `C_(2)H_(5)NO_(2)`

SOLUTION :`C_(2)H_(5)OH+PCl_(5) rarr underset((A))(C_(2)H_(5)Cl)+POCl_(3)+HCl`
`C_(2)H_(5)Cl+AgNO_(2) rarr underset((B))(C_(2)H_(5)NO_(2))+AgCl`


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