1.

Experimentally it was found that a metal oxide has formula M_0.98 O. Metal M is present as M^(2+) and M^(3+) in its oxide. Fraction of the metal which exists as M^(3+) would be

Answer»

`5.08%`
`7.01%`
`4.08%`
`6.05%`

Solution :The FORMULA `M_0.98 O` shows that if there were 100 O-atoms present as `O^(2-)` ions, then there 98 M atoms present as `M^(2+)` and `M^(3+)` . Suppose `M^(3+) =x` , then `M^(2+)` =98-x . As the compound as a WHOLE is neutral, TOTAL charge on `M^(3+)` and `M^(2+)` =Total charge on 100 `O^(2-)` ions
x (+3) + (98-x) (+2)=100 x 2 or 3x + 196 - 2x =200 or x=4
`THEREFORE` % of `M^(3+)=4/98xx100`=4.08 %


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