1.

Experimentally it was found that a metal oxide has formulaM_(0.98)O. Metal M is present asM^(2+) and M^(3+) in iyts oxide. Fraction of the metal which exists asM^(3+)would be

Answer»

0.0508
0.0701
0.0408
0.0605

Solution :The formula ` M_(0.98)O` shows that if there were 200 O-ATOMS present as ` O^(2-)` IONS, then there98 M atoms present as ` M^(2+) and M^(3+)` . Suppose`M^(3+) =X "then" M^(2+) = 98-x`. As the compound as a whole is netural .
total charge on `M^(3+) and M^(2+)`= Total charge on ` 100 O^(2-) ` ions
x (+3)+ ( 98-x) (+2) = 100 `xx`2
or 3 x + 19 6- 2 x = 200 or x = 4
% of ` M^(3+) = 4/98 xx 100 = 4.08 %`


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