1.

Experimentally it was found that a metal oxide has formula M_(0.98)O. Metal M ispresented as M^(2+) and M^(3+) in its oxide. Fraction of the metal which exists as M^(3+) would be

Answer»

`5.08%`
`7.01%`
`4.08%`
`6.05%`

Solution :The FORMULA `M_(0.98)O` shows that if there were 100 O atoms present as `O^(2-)`ions, than 98 M atoms will be present as `M^(2+) and M^(3+)`. Suppose `M^(3+)`= x then `M^(2+)`=98-x. As the compound as a WHOLE is NEUTRAL , the total CHARGE on `M^(3+) and M^(2+)` = totalcharge on 100 `O^(2-) ion`
`x(+3)times(98-x)TIMES2=(100)times2`
`3x+196-2x=200therefore x=2`
`therefore % "of "M^(3+)=4/98times100=4.08%`


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