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Explain Aluminothermic process. |
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Answer» Metallic oxides such as Cr2O3 can be reduced by an aluminothermic process. In this process, the metal oxide is mixed with aluminium powder and placed in a fire clay crucible. To initiate the reduction process, an ignition mixture (usually magnesium and barium peroxide) is used. BaO2 + Mg ⟶ BaO + MgO During the above reaction a large amount of heat is evolved (temperature upto 2400°C, is generated and the reaction enthalpy is - 852 kJ mol) which facilitates the reduction of Cr2O3 by aluminium power. Cr2O3 + 2Al + Δ ⟶ 2Cr+ Al2O3 |
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