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Explain common ion effect with an example.

Answer»

Common Ion Effect: When a salt of a weak acid is added to the acid itself, the dissociation of the weak acid is suppressed further. Acetic acid is a weak acid. It is not completely dissociated in aqueous solution aid hence the following equilibrium exists.

CH3COOH (aq) ⇌ H+ (aq)+ CH3OO- (aq) 

However, the added salt, sodium acetate, completely dissociates to produce Na+ and CH3COO- ion. 

CH3COONa (aq) → Na+ (aq) + CH3COO- (aq) . 

Hence, the overall concentration of CH3COO- is increased, and the acid dissociation equilibrium is disturbed. We know from Le chatelier’s principle that when a stress is applied to a system at equilibrium, the system adjusts itself to nullify the effect produced by that stress. So, in order to maintain the equilibrium, the excess CH3COO- ions combines with H+ ions to produce much more unionized CH3COOH i.e., the equilibrium will shift towards the left. In other words, the dissociation of CH3COOH is suppressed. Thus, the dissociation of a weak acid (CH3COOH) is suppressed in the presence of a salt (CH3COONa) containing an ion common to the weak electrolyte. It is called the common ion effect.



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