1.

Explain giving reasons:(i) Transition metals and many of their compounds show paramagnetic behaviour.(ii) The enthalpies of atomisation of the transition metals are high.(iii) The transition metals generally form coloured compounds.(iv) Transition metals and their many compounds act as good catalyst.

Answer»

(i) Paramagnetic arises due to the presence of unpaired electrons, each such electron has a magnetic moment associated with it due to its spin angular momentum. Transition metals have in its ground state or ionised state have number of unpaired d-electrons which gives it a paramagnetic behaviour.

(ii) Transition metals have very high interatomic metallic interaction due to the involvement of greater number of electrons from (n - 1)d in addition to the ns electrons. Greater the number of valence electrons, stronger is the resultant bonding due to the greater overlapping of half filled orbitals. Hence, more amount of energy is required to break these metallic bond. Thus enthalpy of atomisation of transition metal is very high.

(iii) Colour of transition metal - compounds is due to the excitation of an electron from a lower energy d-orbital to a higher energy d orbital. The energy of excitation corresponds to the frequency of light absorbed and the colour observed corresponds to the complementary colour of the light absorbed (whose frequency lies on the visible region). The frequency of the light absorbed depends on the nature of ligand. Transition metals form coloured compounds due to presence of vacant d-orbitals for the d-d transition of e’ which causes the colour.

(iv) The catalytic activity of transition metals is ascribed to their’ability to adopt multiple oxidation states and to form complexes. Catalyst at a solid surface involve the formation of bonds between reactant molecules and atoms of the surface of the catalyst this has the effect of increasing the concentration of the reactants at the catalyst surface and also weakening of the bonds in the reacting molecules (activation energy is lowered. Transition metals have d and s orbitals to from these bonds.



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