1.

Explain preparation of acidic buffer solution with example.

Answer»

Solution :With the help of `pK_a` and `pK_a` of acid and base the ratio of salt acid or salt and base regulated and buffer solution is prepare .
For preparation of acidic butter weak acid HA and its salt with strong base is taken , the pH of solution is given by -
`pH=pK_a + "log" ([A^-])/([HA])`
If `[HA]=[A^-]` than log `([A^-])/([HA])`= log 1=0
`therefore pH=pK_a`
Hence if weak and CONJUGATE base have same concentration than pH is equal to `pK_a`. "So to prepare buffer with desire pH SELECT such acid whose `pK_a` value is near to pH value."
The `pK_a` of acetic acid is 4.76 . Therefore the pH of buffer SOLUTIONWHICH made by same molar concentration containing solution of acidic acid and sodium acetate , is approximately NEARER to 4.76
To PRODUCE buffer solution, take the concentration of weak acid and its conjugate base equal.


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