1.

Explain the following :(i) CO is stronger ligand than NH3.(ii) Low spin octahedral complexes of nickel are not known.(iii)Aqueous solution of [Ti(H2O)6]+3 is coloured.

Answer»

(i) CO has high value of crystal field splitting energy than Cl.
(ii) Ni has d8 conguration which does not affect by field strength of ligand.
(iii) In this case, Ti+3 has t2g 1 eg 0 configuration. It can perform d-d transition
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