1.

Explain the industrial method for the preparation of ammonia​

Answer»

ANSWER:

Industrial production of ammonia gas is carried out by Habers process. In this method, dihydrogen and dinitrogen gases are mixed in 3:1 proportion by volume and then passed over iron CATALYST at 200-300 bars of pressure. A temperature of about 773 K is MAINTAINED during this reaction. Substances like Al_2O_3, K_2OAl

2

O

3

,K

2

O are added to increase the efficiency of the catalyst. Hence, they are called propmoters. By cooling the reaction mixture at a temperature lower than 273 K, ammonia can be separated from the unreacted N_2N

2

and H_2H

2

gases. Thus, ammonia is obtained in the liquid form and N_2N

2

and H_2H

2

remain without reaction and can be used again to take part in the reaction.

N_2(g)+3H_2(g) \xrightarrow [200-300 bar / Fe ]{773K} 2NH_3(g) + heatN

2

(g)+3H

2

(g)

773K

200−300bar/Fe

2NH

3

(g)+heat

Physical properties of ammonia: Ammonia is a colourless gas. It possesses a very intensive smell, causing irritation in the nose and the eyes.



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