1.

Explain the mechanism of Friedel craft's acylation reaction.

Answer»

Solution :Benzene REACTS with acetyl chloride in presence of anhydrous `AlCl_(3)` to form acetophenone.

Mechanism
Step 1 : GENERATION of electrophile `CH_(3)CO^(+)`
`CH_(3) - CO - Cl + AlCl_(3) rarr CH_(3) - CO^(+) + AlCl_(4)^(Θ)`
Step 2 : The electrophile `CH_(3)CO^(+)` attacks the benzene RING to form a carbocation which is reasonance stabilized.

Step 3: Loss of proton to GIVE acetophenone.


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