1.

Explain the metalic character of transition metals.

Answer»
  • All the transition elements are metals. 
  • They are hard, lustrous, malleable, ductile and they have high tensile strength. 
  • They have high melting points and boiling points. 
  • Their metallic character is due to vacant or partially filled (n – 1) d-orbitals, and they involve both metallic and covalent bonding. 
  • Since the strength of metallic bonds depends upon the number of unpaired electrons, it increases up to middle i.e., up to (n – 1 )d5, hence accordingly melting points and boiling points also increase. 
  • After (n – l)d5 configuration, the electrons start pairing, hence the metallic strength, melting points and boiling points decrease with the increase in atomic number. 


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