1.

Explain the nature of C- X bond in haloarenes and its resonance structure.

Answer»

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Solution :(i) In haloarenes, the carbon atom is `sp^2` hybridised. The` sp^2` hybridised orbitals are SHORTER and holds the electron pair bond more.
(ii) Halogen atom contain p - orbital with LONE pair of electrons which interacts with `pi` orbitals of benzene RING to form extended conjugated system of `pi`-orbital.
(III) The delocalisation of these electrons give double bond character to C - X bond. The resonance structure of halobenzene are give as :


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