1.

Explain why (a) The angle of contact of mercury with glass is obtuse , while of water with glass is acute .

Answer»

Solution :Let a drop of a LIQUID (L) is on a solid surface S PLACED in AIR A. The air is the medium around drop . The surface tensions are SHOWN on drop .

`S_(SL)=` The surface tension corresponding to solid -liquid layer .
`S_(LA)` = The surface tension corresponding to liquid - air layer.
`S_(SA)` = The surface tension corresponding to solid - air layer.
`theta` = angle of contact
`S_(LA)costheta+S_(SA)=S_(SL)`
For the mercury glass interface , `S_(SA)ltS_(SL)`Therefore , `costheta` is negative . Thus `theta` is an acute angle.


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