1.

Explain why: (i) Transition elements form alloys.(ii) Zn2+ salts are white whereas Cu2+ salts are coloured. (iii) Transition metals and their compounds act as a catalyst.

Answer»

(i) This is because transition metals have similar atomic radii and form substitutional alloys.

(ii) Zn2+(3d10) salts have no impaired electrons but Cu2- (3d9) salts have one unpaired electrons. Hence Zn2+ salts are white while Cu2- salts are coloured.

(iii) This is because of transition metals

• have a number of unpaired electrons in their (n-1) d-orbitals

• can show variable oxidation states.

• form intermediates and provide a new reaction path having lower energy of activation.

• they can adsorb one of the reactants on their surfaces.



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